Scorpionates are versatile and flexible ligands with a wide range of applications including catalysis, C-H bond activation, formation of new class of materials, and mimicking enzymatic reactions. This is as a result of its steric and electronic properties, and due to the relative ease with which the 3, and 5-positions of the pyrazole ring can be functionalized. In this work, we report the synthesis of a new class of scorpionate ligands known as cyanoscorpionates which can crosslink various metal centers. Thus, bis (4-cyano-3,5-diphenylpyrazolyl)borate BpPh2,4CN was synthesized and fully characterized by 1H NMR and FT-IR. Coordination of bis (4-cyano-3,5-diphenylpyrazolyl)borate BpPh2,4CN to thallium (I) metal was performed and characterized and we are looking to elucidating its molecular structure by X-ray crystallography in future.
Identifer | oai:union.ndltd.org:ETSU/oai:dc.etsu.edu:etd-4546 |
Date | 01 December 2016 |
Creators | Acquah, Chris |
Publisher | Digital Commons @ East Tennessee State University |
Source Sets | East Tennessee State University |
Language | English |
Detected Language | English |
Type | text |
Format | application/pdf |
Source | Electronic Theses and Dissertations |
Rights | Copyright by the authors. |
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