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The Determination of Organic-Bound Chlorine Levels in Municipal Wastewaters After Treatment with Heavy Chlorine Doses

The development of an analytical method for the determination of total organic-bound chlorine (TOCl) produced during the chlorination of municipal wastewater effluents is presented. Sewage effluent from the Denton, Texas municipal treatment plant was chlorinated at high chlorine doses (1000 - 4000 ppm), as well as typical treatment levels. Chlororganics present in the wastewater, before and after chlorination, were concentrated by adsorption on Amberlite XAD-2 macroreticular resin, followed by elution with diethyl ether. After concentration, the extracts were analyzed for TOC1 by microcoulometry.
Analysis of wastewater extracts revealed the production of substantial amounts of new chlorinated organics when effluents were treated with chlorine. The method shows good precision and estimated accuracy is favorable.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc504486
Date05 1900
CreatorsSmith, Garmon B.
ContributorsGlaze, William, Jacobson, Myron, Stanford, Jack Arthur, 1947-
PublisherNorth Texas State University
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatv, 93 leaves : ill., Text
RightsPublic, Smith, Garmon B., Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved.

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