We describe the oxygenation of tertiary arylamines, and the amination of tertiary arylamines and phenols. The key step of these coupling reactions is an iron-catalyzed oxidative C−O or C−N bond formation which generally provides the corresponding products in high yields and with excellent regioselectivity. The transformations are accomplished using hexadecafluorophthalocyanine−iron(II) (FePcF16) as catalyst in the presence of an acid or a base additive and require only ambient air as sole oxidant.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:91264 |
| Date | 04 June 2024 |
| Creators | Purtsas, Alexander, Rosenkranz, Marco, Dmitrieva, Evgenia, Kataeva, Olga, Knölker, Hans-Joachim |
| Publisher | Wiley-VCH |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | 1521-3765, e202104292, 10.1002/chem.202104292, info:eu-repo/grantAgreement/Deutsche Forschungsgemeinschaft/Green and Sustainable Catalysts for Synthesis of Organic Building Blocks/KN 240/19-2/ |
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