When deoxybenzoin oxime was reacted with carbon monoxide and hydrogen in the presence of dicobalt ootacarbonyl at elevated temperatures and pressures 3-benzylphthalimidine and 3-phenyl-3,4-dihydroisocarbostyryl were produced.
When 2-acetonaphthone oxime was reacted under similar conditions 2-(β-naphthyl)-4-methyl-benzo[h] quinoline, 3-methylbenzo[f]phthalimidine and
1- (β-naphthyl)ethylurea were produced. Verification of the structure of 2-(β-naphthyl)-4-methylbenzo[h]-quinoline was attained in part through the hydrochloride salt, the methiodide salt, the picrate derivative and the 2-(β-naphthyl)-4-formylbenzof[h]-quinoline derivative. 2-(β-Naphthyl)-4-methyl-benzof[h] quinoline was also synthesized by reacting 2- acetonaphthone oxime with 2-acetonaphthone at elevated temperatures.
The infrared spectra of the above compounds are described. / Science, Faculty of / Chemistry, Department of / Graduate
| Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/40267 |
| Date | January 1959 |
| Creators | Hubscher, Arthur Ronald |
| Publisher | University of British Columbia |
| Source Sets | University of British Columbia |
| Language | English |
| Detected Language | English |
| Type | Text, Thesis/Dissertation |
| Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
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