A series of 2-substituted 8-hydroxyquinolines have been prepared and their reactions with a number of metal ions studied. Acid-dissociation constants and metal-chelate formation constants have been determined. 2-(2'-Hydroxyphenyl), 2-(2'-pyridyl) and 2-hydrazino-8-hydroxyquinoline function as terdentate ligands. The latter two ligands form a number of protonated complexes some of which are unusually stable. This stability is likely due to hydrogen bonding. / Thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/17507 |
| Date | 09 1900 |
| Creators | Cassidy, Richard M. |
| Contributors | Corsini, A., Chemistry |
| Source Sets | McMaster University |
| Language | English |
| Detected Language | English |
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