<p> The purpose of this research is to synthesize novel Dinitrosyl-Iron Complexes and to investigate their structures and properties. It is hoped that the compounds may be used for nitric oxide releasing agents in the biological system. Three novel Dinitrosyl-Iron Complexes of bridged bis-phophine ligands were synthesized. Syntheses of the compounds were performed in the glove box under a nitrogen environment. The synthesized compound has general molecular formula of Fe<sub> 2</sub>(NO)<sub>4</sub>(CO)<sub>2</sub>(L) where (L = (–)-1,2-Bis[(2<i> S</i>,5<i>S</i>)-2,5-dimethylphospholano]ethane, (–)-1,2-Bis((2<i> R</i>,5<i>R</i>)-2,5-diphenylphospholano)ethane, Bis(dicyclohexylphosphino)methane). These compounds were characterized using X-ray crystallography and spectroscopic methods of infrared (IR), ultraviolet-visible (UV-Vis), and nuclear magnetic resonance (NMR). FT-IR spectrum showed the formation of these complexes, UV-Vis analyses demonstrated the compounds characteristics, and the presence of compounds were detected by <sup>1</sup>H and <sup>13 </sup>C NMR.</p>
| Identifer | oai:union.ndltd.org:PROQUEST/oai:pqdtoai.proquest.com:1526960 |
| Date | 25 November 2014 |
| Creators | Sytwu, Karol L. |
| Publisher | California State University, Long Beach |
| Source Sets | ProQuest.com |
| Language | English |
| Detected Language | English |
| Type | thesis |
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