by Cheng Pui Shan. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2004. / Includes bibliographical references. / Abstracts in English and Chinese. / Abstract --- p.i / 摘要 --- p.iii / Acknowledgement --- p.iv / Table of Contents --- p.v / List of Compounds --- p.viii / Abbreviations --- p.xi / Chapter Chapter 1. --- A General introduction to Metal amides / Chapter 1.1 --- introduction / Chapter 1.1.1 --- General Background --- p.1 / Chapter 1.1.2 --- Metal Complexes with 2-Pyridyl Amido Ligands --- p.2 / Chapter 1.2 --- OBJECTIVES OF THIS WORK --- p.4 / Chapter 1.3 --- references for chapter1 --- p.5 / Chapter Chapter 2. --- Group 13 metal Amides / Chapter 2.1 --- GENERAL BACKGROUND --- p.8 / Chapter 2.1.1 --- Common Methods for the Preparation of Group 13 Metal Amides --- p.8 / Chapter 2.1.2 --- "An Overview on Aluminum(III), Gallium(III) and Indium(III) Amides" --- p.9 / Chapter 2.1.3 --- An Overview on Aluminum(III) Aryloxides --- p.15 / Chapter 2.2 --- aims of our studies --- p.18 / Chapter 2.3 --- results and discussion --- p.19 / Chapter 2.3.1 --- Preparation of [HN(SiButMe2)(2-C5H3N-6-Me)] (HL1) and Its Lithium Derivative [LiL1(TMEDA)] --- p.19 / Chapter 2.3.2 --- "Synthesis and Structures of Aluminum(III), Gallium(III) and Indium(III) Amides" / Chapter 2.3.2.1 --- "Synthesis of [MCl(L1)2] (M = Al 3, Ga 4) and [In(L1)3] (5)" --- p.20 / Chapter 2.3.2.2 --- Physical Characterization of Compounds 3-5 --- p.21 / Chapter 2.3.2.3 --- Molecular Structures of Compounds 3-5 --- p.24 / Chapter 2.3.3 --- Reactivity Studies --- p.35 / Chapter 2.3.3.1 --- Physical Characterization of Compounds 6 and7 --- p.38 / Chapter 2.3.3.2 --- Molecular Structures of Compounds 6 and7 --- p.39 / Chapter 2.4 --- EXPERIMENTALS FOR CHAPTER2 --- p.47 / Chapter 2.5 --- REFERENCES FOR CHAPTER2 --- p.52 / Chapter Chapter 3. --- A Silyl´ؤlinked diamine compound and its metal complexes / Chapter 3.1 --- A GENERAL INTRODUCTION TO DIAMINE COMPOUNDS --- p.59 / Chapter 3.2 --- A GENERAL INTRODUCTION TO MIXED ALKALI METAL AMIDES --- p.65 / Chapter 3.3 --- AIMS OF OUR STUDIES --- p.67 / Chapter 3.4 --- SYNTHESIS AND STRUCTURES OF [Me2Si{NH(2-Py)}2] AND THE CORRESPONDING ALKALI METAL AMIDES / Chapter 3.4.1 --- Synthesis and Structure of [Me2Si{NH(2-Py)}2] (HL2) (8) --- p.68 / Chapter 3.4.2 --- Synthesis and Structures of Alkali Metal Amides / Chapter i. --- Synthesis of Sodium Derivatives of8 --- p.74 / Chapter ii. --- Synthesis of a Mixed Alkali Metal Derivative of8 --- p.75 / Chapter iii. --- Attempted Metallation of 8 with KBun --- p.75 / Chapter iv. --- Physical Characterization --- p.77 / Chapter v. --- Molecular Structures --- p.80 / Chapter 3.5 --- synthesis and structure of the iron(ii) derivative [Fe(L2)Cl]2 / Chapter 3.5.1 --- An Overview on Iron(II) Amides --- p.95 / Chapter 3.5.2 --- Aims of Our Studies --- p.97 / Chapter 3.5.3 --- Synthesis and Structure of [FeCl(L2)]2 (14) / Chapter i. --- Synthesis and Characterization --- p.98 / Chapter ii. --- Molecular Structure --- p.99 / Chapter 3.6 --- EXPERIMENTALS FOR CHAPTER 3 --- p.102 / Chapter 3.7 --- REFERENCES FOR CHAPTER 3 --- p.106 / APPENDIX 1 / General Procedures and Physical Measurements --- p.110 / X-Ray Crystallography --- p.110 / APPENDIX 2 / Table A-1. Selected crystallographic data for compounds 3-5. --- p.113 / Table A-2. Selected crystallographic data for compounds 6´ؤ7. --- p.114 / Table A-3. Selected crystallographic data for compounds 8，10-11. --- p.115 / Table A-4. Selected crystallographic data for compounds 12-14. --- p.116
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_324874 |
| Date | January 2004 |
| Contributors | Cheng, Pui Shan., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xi, 116 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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