The reactions of organomagnesium akoxides EtMgOR (R= Me, Et) with dialkynyl magnesium complexes Mg(CoCR¢F) (R¢F= tBu, SiMe3) give a series of the tetranuclear magnesium complexes [Mg4(OR)2Et2(CoCR¢F)4(THF)4] (R= Me, Et; R¢F= tBu, SiMe3).
The reactions of diethyl magnesium complexes MgEt2 with alkynes HCoCR (R= tBu, SiMe3) give two different kinds magnesium complexes. One kind is [Mg4(OEt)2-Et2(CoCR)4(THF)4] (R= tBu, SiMe3); another kind is [Mg4O(CoCR)6(THF)4] (R= tBu, SiMe3).
Besides, the reaction of diisopropylamide magnesium complex Mg(NiPr2)2 with alkyne HCoCtBu give first example including two different kind bridge ligands trinuclear magnesium complex Mg3(NiPr2)2(CoCtBu)4(THF)2.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0725100-215537 |
| Date | 25 July 2000 |
| Creators | Lin, Chih-Chieh |
| Contributors | Chung-cheng Chang, Tsu-hsin Chang, Kom-Bei Shiu, Yen-nan Chiang |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0725100-215537 |
| Rights | unrestricted, Copyright information available at source archive |
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