1. The acid catalyzed cyclodehydration method was extended to the 9-aryl-1,2-benzanthracene and 9-naphthylanthracene series.
2. A new method of cyeclodehydration was described.
3. The series of 10-mono- and 10-dimethylphenyl-1,2-benzanthracenes was completed. All the isomeric 9-mono- and 9-dimethylphenyl-1,2-benzanthracenes were prepared together with the corresponding ketones. Some highly hindered ketones were prepared and their cyclization realized. A total of 47 compounds, not previously reported in the literature, were synthesized.
4. The spectra of 24 hydrocarbons were recorded and the theory of nonplanarity of these compounds substantiated. / Ph. D.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/37187 |
| Date | 12 January 2010 |
| Creators | Borkovec, Alexej B. |
| Contributors | Chemistry, Vingiello, Frank A., Murray, John W., King, Kendall W. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | English |
| Detected Language | English |
| Type | Dissertation, Text |
| Format | 145 leaves, BTD, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 20499636, LD5655.V856_1955.B674.pdf |
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