This paper deals with the problem of setting up an infrared spectrometer and recorder under suitable conditions, and in applying the instrument to the absorption spectrum of CS₂ in the vapor phase.
Six absorption bands, corresponding to the fundamental vibration V₃ at 1535 cm⁻¹, the difference band V₃ - V₁, at 877 cm⁻¹, and the four combination bands V₁ + V₃ at 2185 cm⁻¹, V₃ + 2V₂ at 2332 cm⁻¹, V₃ +2V₁ at 2838 cm⁻¹, and V₁ + V₃ + 2V₂ at 2959 cm⁻¹ have been examined.
Using this value for V₃, a better agreement between the force constant of the C S bond, calculated from V₃, with that calculated from V₁, is obtained.
The work is to be continued. / Science, Faculty of / Physics and Astronomy, Department of / Graduate
| Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/41688 |
| Date | January 1948 |
| Creators | Edwards, Thomas Harvey |
| Publisher | University of British Columbia |
| Source Sets | University of British Columbia |
| Language | English |
| Detected Language | English |
| Type | Text, Thesis/Dissertation |
| Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
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