Lau Cheuk Man. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references (leaves 93-98). / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgements --- p.iii / Abbreviations --- p.iv / Structural Abbreviations for Porphyrin Complexes --- p.v / Abstract --- p.vi / Chapter Chapter 1 --- Introduction / Chapter 1.1 --- General Introduction --- p.1 / Chapter 1.2 --- Activation of Carbon-Hydrogen Bond (CHA) by Transition Metal --- p.2 / Chapter 1.2.1 --- Application of CHA by Transition Metals --- p.3 / Chapter 1.2.2 --- Thermodynamic in CHA by Transition Metals --- p.5 / Chapter 1.2.3 --- Types of Carbon-Hydrogen Activations --- p.6 / Chapter 1.3 --- Carbon-Hydrogen Bond Activation of Aldehydes --- p.14 / Chapter 1.3.1 --- Catalytic Application of CHA of Aldehydes by Transition Metals --- p.14 / Chapter 1.3.2 --- Stability of Intermediate M(COR) --- p.15 / Chapter 1.3.3 --- Issue in Selectivity --- p.16 / Chapter 1.4 --- Structural Features of Rhodium Porphyrins --- p.23 / Chapter 1.5 --- Objective of the work --- p.24 / Chapter Chapter 2 --- Carbon-Hydrogen Activation of Aldehydes by Rh(ttp)Cl and Rh(ttp)Me / Chapter 2.1 --- Introduction --- p.26 / Chapter 2.2 --- CHA of Aldehydes by Rh(ttp)Cl --- p.27 / Chapter 2.2.1 --- Preparation of Rh(ttp)Cl --- p.27 / Chapter 2.2.2 --- Solvents Screening --- p.27 / Chapter 2.2.3 --- Results and Discussion --- p.30 / Chapter 2.3 --- CHA of Aldehydes by Rh(ttp)Me --- p.33 / Chapter 2.3.1 --- Preparation of Rh(ttp)Me --- p.34 / Chapter 2.3.2 --- Results and Discussion --- p.35 / Chapter 2.4 --- Mechanistic Studies --- p.37 / Chapter 2.4.1 --- CHA of Aldehydes by Rh(ttp)Cl --- p.37 / Chapter 2.4.2 --- CHA of Aldehydes by Rh(ttp)R --- p.42 / Chapter 2.5 --- Comparison of the u(C=0) --- p.48 / Chapter 2.6 --- X-ray Data --- p.49 / Chapter 2.7 --- Summary --- p.50 / Chapter Chapter 3 --- CHA of Aldehydes by Rh(ttp)CH2CH2OH and Rh(ttp)+X- / Chapter 3.1 --- Introduction --- p.52 / Chapter 3.2 --- CHA of Aldehydes by Rh(ttp)CH2CH2OH --- p.53 / Chapter 3.2.1 --- Results and Discussion --- p.53 / Chapter 3.2.2 --- Mechanistic Studies --- p.61 / Chapter 3.3 --- CHA of Aldehydes by Rh(ttp)+X- --- p.65 / Chapter 3.4 --- Summary --- p.67 / Conclusion --- p.68 / Experimental --- p.69 / Reference --- p.93 / Appendix I Crystal Data and Processing Parameters --- p.99 / List of Spectra --- p.141 / Spectra --- p.143
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325274 |
| Date | January 2005 |
| Contributors | Lau, Cheuk Man., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, vii, 166 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
Page generated in 0.0021 seconds