The potassium pentafluorophenylfluoroborates were prepared by hydroxy-fluoride-substitution of fluoroorganoalkoxyboranes and -borates with potassium bifluoride. Those intermediate boranes and borates were obtained by the reaction of fluoroorganomagnesium reagents and alkoxyboranes. The introduction of one or two pentafluorophenylgroups into various alkoxyboranes is investigated to optimize the yield of potassium pentafluorophenyltrifluoroborate and bis(pentafluorophenyl)difluoroborate. Reactions of pentafluorophenylfluoroborates with the Lewis acids borontrifluoride and tris(pentafluorophenyl)borane show the Lewis acidity of pentafluorophenyldifluoroborane compared with borontrifluoride and tris(pentafluorophenyl)borane. Pentalfuorophenylfluoroborate salts reacted with iodinepentafluoride by transfer of a pentafluorophenylgroup to iodinepentafluoride. To develop an alternative method to fluorooganofluoroborates systematic investigations on the reactivity of fluoroorganoboranes to fluorides were undertaken. Potassium-1H,1H,2H,2H-perfluorooctyltrifluoroborate is prepared by the reaction of an organogrignard reagent with chlorodimethoxyborane and hydrolysis and hydoxy-fluoride-substitution of the product. Treatment of the borate wit borontrifluoride provides the corresponding difluoroborane with ponytailgroup.
| Identifer | oai:union.ndltd.org:DUETT/oai:DUETT:duett-05312003-191703 |
| Date | 06 June 2003 |
| Creators | Fritzen, Petra |
| Contributors | Prof. Dr. H. Willner, Prof. Dr. H.-J. Frohn |
| Publisher | Gerhard-Mercator-Universitaet Duisburg |
| Source Sets | Dissertations and other Documents of the Gerhard-Mercator-University Duisburg |
| Language | German |
| Detected Language | English |
| Type | text |
| Format | text/html, application/pdf |
| Source | http://www.ub.uni-duisburg.de/ETD-db/theses/available/duett-05312003-191703/ |
| Rights | unrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. Hiermit erteile ich der Universitaet Duisburg das nicht-ausschliessliche Recht unter den unten angegebenen Bedingungen, meine Dissertation, Staatsexamens- oder Diplomarbeit, meinen Forschungs- oder Projektbericht zu veroeffentlichen und zu archivieren. Ich behalte das Urheberrecht und das Recht das Dokument zu veroeffentlichen und in anderen Arbeiten weiterzuverwenden. |
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