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Applying velocity constraints to the laser spectroscopy of deuterium-atom and chlorine-atom photodissociation products

The nuclear hyperfine population distributions of the deuterium atom produced in the 266 nm photolysis of DI were measured with a technique that applies spatial filtering of the nascent recoiling photoproducts to yield a reduced Doppler profile. A novel method of resonance detection for Cl atom photoproducts is also presented along with time-of-flight measurements of chlorine atoms as photoproducts from the dissociation of Cl2, thiophosgene, and phosgene. The resonance detection method permits high-resolution frequency scanning of the hyperfine structure of the chlorine atom. The results of these measurements are also presented / acase@tulane.edu

  1. tulane:27200
Identiferoai:union.ndltd.org:TULANE/oai:http://digitallibrary.tulane.edu/:tulane_27200
Date January 2005
ContributorsJohnson, Michael W (Author), Koplitz, Brent (Thesis advisor)
PublisherTulane University
Source SetsTulane University
LanguageEnglish
Detected LanguageEnglish
RightsAccess requires a license to the Dissertations and Theses (ProQuest) database., Copyright is in accordance with U.S. Copyright law

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