The preparation of the first complex compound of BF3, BF3, NH3, was reported by Gay-Lussac and Thenard (1) more than 150 years ago. Some time afterwards the first SiF4 complex, SiF4.2NH3, was prepared (2). In 1890, Besson (3) isolated crystalline SiF4.PH3, but a temperature of -22° and a pressure of SO atmospheres were necessary. This is the only SiF4 complex reported containing a phosphorus electron-pair donor molecule and none have been reported with sulfur electron-pair donor molecules. [...]
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.117592 |
| Date | January 1965 |
| Creators | Guertin, Jacques Peter. |
| Contributors | Onyszchuk, M. (Supervisor) |
| Publisher | McGill University |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Format | application/pdf |
| Coverage | Doctor of Philosophy (Department of Chemistry) |
| Rights | All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. |
| Relation | alephsysno: NNNNNNNNN, Theses scanned by McGill Library. |
Page generated in 0.0019 seconds