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THE SYNTHESIS OF CATIONIC BIS(ETA(6)-ARENE)MANGANESE SANDWICH COMPLEXES

The use of elemental iodine as an in situ oxidant allows the metal vapor synthesis of bis($\eta\sp 6$-arene)manganese cationic sandwich complexes from alkyl substituted arenes. These stable 18 electron species are isolated as hexafluorophosphate salts. $\sp 1$H NMR, $\sp{13}$C NMR, and FABMS spectra were secured for each compound.

Identiferoai:union.ndltd.org:RICE/oai:scholarship.rice.edu:1911/13243
Date January 1987
CreatorsMOOREHEAD, A. W.
Source SetsRice University
LanguageEnglish
Detected LanguageEnglish
TypeThesis, Text
Formatapplication/pdf

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