Bioremediation of chlorinated aliphatic hydrocarbon (CAH) compounds commonly found at contaminated sites has been an area of focus in recent years. The cometabolic transformation of CAH compounds is important at sites where the redox condition does not favor natural attenuation or populations of indigenous microorganisms are relatively low. At sites where the ground-water system is aerobic, monitored natural attenuation strategies will not meet remediation objectives, or both, enhanced bioremediation via cometabolism is an option. Models are needed to simulate cometabolism in an effort to improve performance and design. The SEAM3D Cometabolism Package was designed to address this need. The objective of this report is to model field data to determine the ability of SEAM3D to simulate the performance of cometabolism. A ground-water flow and transport model was designed based on reported parameters used in the field experiments at Moffett Field. Electron donor and acceptor breakthrough curves were also simulated in an effort to calibrate the model. Several data sets describing the cometabolism of CAHs were used in the cometabolism modeling for calibration to field data. The cometabolism modeling showed areas of best fit calibration with modification to the model parameters reported for the pilot tests at Moffett Field. The overall performance of the SEAM3D Cometabolism Package described in this report establishes validation of the model using field experiment results from the literature. Additional model validation is recommended for other contaminants. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/37103 |
| Date | 21 May 2003 |
| Creators | Brewster, Ryan Jude Stephen |
| Contributors | Civil Engineering, Widdowson, Mark A. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Detected Language | English |
| Type | Master's project |
| Format | application/pdf, application/pdf, application/pdf |
| Rights | I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to Virginia Tech or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report. |
| Relation | Title.pdf, tablecontents.pdf, mainpaper.pdf |
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