The effects of transition metal ions as components of the mobile phase on the retentions in HPLC of 2-aminophenol and selected α-diketones were studied on both ODS-silica and porous polymer columns. The compounds were used as model compounds in an investigation which set out to derive a detailed understanding of the mechanisms Involved when metal ions are used to selectively modify the retention of compounds capable of interaction. This technique, which has parallels with ion-pair chromatography, provides another method by which the conditions of a separation may be altered and the selectivity adjusted to give better resolution.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:381449 |
| Date | January 1988 |
| Creators | Bale, Simon J. |
| Publisher | Loughborough University |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | https://dspace.lboro.ac.uk/2134/27578 |
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