Nonlinear organic liquids that exhibit two-photon absorption (TPA) function as good optical limiters for sensor protection from laser pulses. L34 (4-butyl-4'-propyl-diphenylethyne) is a liquid organic compound exhibiting nonlinear optical absorption. A thiol- derivatized analog of L34 (“thiol-L34”) was prepared to bind the molecules to the surface of gold nanoparticles. Surface binding is necessary to investigate synergy between nonlinear optical absorption of gold nanoparticles and thiol-L34. Thiol-L34 was prepared in a six-step organic synthesis starting from 3-(4-bromophenyl) propionic acid. Au nanoparticles with <15 nm diameter have been prepared and sensitized with the thiol-L34 compound for assessment of their nonlinear optical behavior. Diazolylmethenes a class of metal-coordinating dyes that are similar to dipyrrins with some substitutions of nitrogen atoms in place of carbon atoms. Modification in the framework of dipyrrinoid dyes via this replacement of nitrogen for carbon atoms may lead to compounds that serve as effective agents for bioimaging and/or photodynamic therapy. Several routes to the synthesis of di-(1,2,3)-triazolylmethenes, di-(1,2,4)-triazolylmethenes, and ditetrazolylmethenes are presented.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc699844 |
| Date | 12 1900 |
| Creators | Pokharel, Sundari D. |
| Contributors | Youngblood, W. Justin, Cundari, Thomas R., Omary, Mohammad A., Petros, Robby A., Khoo, Iam-Choon |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | x, 100 pages : illustrations (some color), Text |
| Rights | Public, Pokharel, Sundari D., Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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