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Previous issue date: 2013-03-08 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / Were synthesized spinel-type ferrites with general formula Ni0,8Mg0.2-xMxFe2O4,
where M represents the doping Mn, Co or Mn + Co simultaneously, x ranges for the values
0.02, 0.05 and 0.1. The value of x was divided by 2 in cases where M equals Mn and Co
conjugates. We used the citrate precursor method and heat treatment to obtain the phases at
1100?C. The materials were characterized by XRD, TGA/ DTGA, SEM, MAV and
reflectivity measurements by the method of waveguide. Powders to 350?C/3.5 h were
crystalline and nanosized. According to the results this temperature all powders have a
percentage of ferrite phase over 90%. The composition had the addition of Mn and Co
simultaneously showed a higher percentage of secondary phase NiO, 5.8%. The TGA/DTGA
curves indicate that this sample reached phase (s) crystalline (s) at lowest temperatures. The
X-ray diffractograms of the samples calcined at 350?C and 1100?C were treated with the
Rietveld refinament technique. The powders calcined at 1100 ?C/3h in air show to be 100%
except spinel phase composition with 0.02 doping. The micrographs show clusters of particles
with sizes smaller than 1 μm in calcination temperature of 1100?C which agreed with the
result of Rietveld refinement. In the compositions doped with Mn were higher values of
magnetization (45.90 and 53.20 Am2/kg), which did not cause high microwave absorption.
The theoretical calculation of magnetization (MT) was consistent with the results, considering
that there was agreement between the increase of magnetization experimental and theoretical.
It was observed that there was the interrelation of the final effect of absorption with the
thickness of MARE, the composition of ferrimagnetic materials and in particular the specific
values of frequency. The analysis shows that the reflectivity increases in the concentration of
cobalt increased the frequency range and also for absorption 10.17 GHz and 84%,
respectively. The best result of chemical homogeneity and the value of 2.96 x 10-2 tesla
coercive field were crucial for high performance ferrite absorber with 0.1 cobalt. The Cobalt
has high magnetocrystalline anisotropy, it is associated with an increased coercive field, Hc.
Therefore, this property improves the results of reflectivity of spinel ferrites / Foram sintetizadas ferritas do tipo espin?lio com f?rmula geral Ni0,8Mg0,2-xMxFe2O4,
onde M representa os dopantes Mn, Co ou Mn + Co simultaneamente, x varia para os valores
0,02; 0,05 e 0,1. O valor de x foi dividido por 2 nos casos em que M equivale a Mn com Co
conjugados. Foi utilizado o m?todo dos citratos precursores e tratamento t?rmico na obten??o
das fases a 1100?C. Os materiais foram caracterizados por DRX, TGA/DTGA, MEV, MAV e
medidas de refletividade pelo m?todo de guia de ondas. Os p?s a 350?C/3,5h foram cristalinos
e nanom?tricos. De acordo com os resultados nesta temperatura todos os p?s apresentam um
percentual de fase ferrita superior a 90%. A composi??o que teve a adi??o de Mn e Co
simultaneamente apresentou maior percentual de fase secund?ria NiO, 5,8%. As curvas
TGA/DTGA indicam que essa amostra alcan?ou fase(s) cristalina(s) em temperaturas mais
baixas. Os difratogramas de raios X das amostras calcinadas a 350?C e 1100?C foram tratados
pela t?cnica de refinamento Rietveld. Os p?s calcinados a 1100?C/3h em atmosfera ambiente
mostram ser 100% de fase espin?lio exceto a composi??o com 0,02 de dopantes. As
micrografias apresentam aglomerados de part?culas com tamanhos menores que 1 μm na
temperatura de calcina??o de 1100?C, o que concordou com o resultado de refinamento
Rietveld. Nas composi??es dopadas com Mn ocorreram os maiores valores de magnetiza??o
(45,90 e 53,20 Am2/kg), o que n?o acarretou alta absor??o de microondas. O c?lculo te?rico
da magnetiza??o (MT) foi coerente com os resultados, considerando-se que houve
concord?ncia entre o aumento das magnetiza??es experimental e te?rica. Observa-se que
houve interrela??o do efeito final de absor??o com a espessura do MARE, a composi??o do
material ferrimagn?tico em particular e os valores espec?ficos de freq??ncia. A an?lise de
refletividade indica que o aumento na concentra??o de cobalto aumentou a faixa de freq??ncia
e a absor??o para 10,17 GHz e 84%, respectivamente. O resultado indica que a melhor
homogeneidade qu?mica e o valor 2,96 x 10-2 tesla de campo coercitivo foram determinantes
para o alto desempenho absorvedor da ferrita com 0,1 de cobalto. O Cobalto tem alta
anisotropia magnetocristalina, isto est? associado ao aumento do campo coercitivo, Hc.
Portanto, essa propriedade melhora os resultados de refletividade das ferritas espin?lio
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/17768 |
| Date | 08 March 2013 |
| Creators | Silva, Jos? Eves Mendes da |
| Contributors | CPF:02168290890, http://lattes.cnpq.br/9213856023536973, Ara?jo, Jos? Humberto de, CPF:24150720444, http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4785558U2, Rezende, Mirabel Cerqueira, CPF:03513454856, http://lattes.cnpq.br/3744737176516322, Lima, Ulisandra Ribeiro de, CPF:02824707437, http://lattes.cnpq.br/0610156933803056, Acchar, Wilson, CPF:50580396720, http://lattes.cnpq.br/5460040602567184, Nasar, Ricardo Silveira |
| Publisher | Universidade Federal do Rio Grande do Norte, Programa de P?s-Gradua??o em Qu?mica, UFRN, BR, F?sico-Qu?mica; Qu?mica |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/doctoralThesis |
| Format | application/pdf |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/openAccess |
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