by Chung Sai Cheong. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. / Includes bibliographical references (leaves 94-99). / DESCRIPTIVE NOTE / ABSTRACT --- p.iii / ACKNOWLEDGEMENTS --- p.v / Chapter CHAPTER ONE: --- INTRODUCTION --- p.1 / Chapter CHAPTER TWO: --- EXPERIMENTAL --- p.6 / Chapter 2.1 --- Synthesis --- p.6 / Chapter 2.2 --- NMR Measurement --- p.6 / Chapter 2.2.1 --- Solid State 59Co NMR --- p.6 / Chapter 2.2.2 --- Solution NMR --- p.7 / Chapter 2.2.2.1 --- 59Co NMR Measurements --- p.7 / Chapter 2.2.2.2 --- 13C NMR Measurements --- p.8 / Chapter 2.3 --- UV-Vis Spectral Measurements --- p.9 / Chapter 2.4 --- Computer Simulation --- p.10 / Chapter CHAPTER THREE: --- QUANTITATIVE CORRELATION OF SHIELDING ANISOTROPY AND NQCC - APPLICATION TO SOLVATION STUDIES OF OCTAHEDRAL COBALT (III)COMPLEXES / Chapter 3.1 --- Introduction --- p.11 / Chapter 3.2 --- Theory --- p.15 / Chapter 3.3 --- Results and Discussion --- p.20 / Chapter 3.3.1 --- The 59Co NMR Powder Spectrum of Diamagnetic Cobalt Complexes --- p.20 / Chapter 3.3.2 --- The Correlation of NQCC with Chemical Shift Anisotropy in the Solid State --- p.34 / Chapter 3.3.3 --- Application of Equation 3.16in Solution Studies --- p.39 / Chapter 3.3.3.1 --- The Chemical Shift --- p.39 / Chapter 3.3.3.2 --- The Effective Correlation Time --- p.48 / Chapter 3.3.3.3 --- The Nuclear Quadrupole Coupling Constant --- p.49 / Chapter 3.4 --- Summary --- p.51 / Chapter CHAPTER FOUR: --- 59Co AND 13C RELAXATION OF Co(acac)3 IN HYDROGEN BONDING (KALOMETHANE) SOLVENTS / Chapter 4.1 --- Introduction --- p.53 / Chapter 4.2 --- Results and Discussion --- p.57 / Chapter 4.2.1 --- The Static NMR Powder Spectrum Co(acac)3 --- p.57 / Chapter 4.2.2 --- Chemical shift --- p.60 / Chapter 4.2.3 --- Relaxation --- p.67 / Chapter 4.2.3.1 --- The 13C Relaxation --- p.67 / Chapter 4.2.3.2 --- The 59Co Relaxation --- p.71 / The Spin Rotation Interaction --- p.71 / The Temperature Behaviour of Relaxa- tion Rate --- p.72 / The Nuclear Quadru- pole Coupling Constant --- p.76 / The Correlation Time --- p.82 / Chapter 4.3 --- Summary --- p.90 / Chapter CHAPTER FIVE: --- CONCLUSION --- p.91 / REFERENCES --- p.94
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_319159 |
| Date | January 1992 |
| Contributors | Chung, Sai Cheong., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Publisher | Chinese University of Hong Kong |
| Source Sets | The Chinese University of Hong Kong |
| Language | English |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xi, 99 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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