The preparative and derivative chemistry of organoborane compounds that contain silicon-nitrogen functional groups is both diverse and synthetically useful. The wide variety of reactions that can occur at boron, in combination with facile cleavage of the Si-N bond, makes them potential precursors to polymeric B-N systems.
We report here on the synthesis, characterization, and reactivity of three representative examples of the title systems of general types 1 and 2. Some of these systems are being studied as the precursors to new types of inorganic-organic hybrid polymers and/or novel ring systems.
| Identifer | oai:union.ndltd.org:TCU/oai:etd.tcu.edu:etd-03162010-123538 |
| Date | 16 March 2010 |
| Creators | Cui, Jian |
| Contributors | Robert H. Neilson |
| Publisher | Texas Christian University |
| Source Sets | Texas Christian University |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf, application/msword |
| Source | http://etd.tcu.edu/etdfiles/available/etd-03162010-123538/ |
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