The 1:1 reaction between MgR2 and diphenylamine gave heteroleptic alkyl
-magnesium amide monomeric compounds [RMgNPh2(THF)2] [R=Et (1) and iPr (2)]. Subsequently, addition of stronger donor solvent HMPA to compound 1 results in the disproportionation reaction to give a bisamidomagnesium crystal [Mg(NPh2)2(HMPA)2] (3). The different size secondary amine HNEt2 or HN(SiMe3)2 reacting with Grignard reagent EtMgBr produced diethylamino-bridging and bromo-bridging Hauser base [(Me3Si)2NMg(£g-Br)(OEt2)]2 (4) and [BrMg(£g-NEt2)(HMPA)]2(5) respectively. Unexpectedly, [(Me3Si)NMg
(£g-OEt)(THF)]2 (6) was obtained from the reaction of MgEt2 and HN(SiMe3)2 in the refluxing THF solution. Additionally, iPrMgBr and MgY2 (Y = iPr, C
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0223101-113628 |
| Date | 23 February 2001 |
| Creators | Yang, Kuo-Ching |
| Contributors | Yu Wang, Ho-Hsiang Wei, Shie-Ming Peng, En-Chi Wang, Tsuh-Sin Chang, Michael Y. Chiang, Chung-Cheng Chang |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0223101-113628 |
| Rights | unrestricted, Copyright information available at source archive |
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