The objective of this study was to synthesize and characterize new energetic polycyclic "cage" compounds.
As part of a program involved in the synthesis of new polynitropolycyclic compounds, 2,6-dinitro-5-methoxy-
7-carbomethoxypentacyclo[5. 3 .0 . 0* • * . CP • i ° . 0* •8]decane has been synthesized. This is a model system which can be used to study (1) the effect of nitro substitution on the photolability of carbon-carbon double bonds and (2) to develop methods for avoiding Haller-Bauer cleavage in cage /3-keto esters when synthesizing polynitro-substituted cage compounds.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc332109 |
| Date | 05 1900 |
| Creators | Jin, Pei-Wen |
| Contributors | Marchand, Alan P., Brady, William Thomas, Jones, Paul R., Theriot, L. J., Wu, Edward Ming-chi, 1938- |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | vi, 133 leaves: ill., Text |
| Rights | Public, Jin, Pei-Wen, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
Page generated in 0.0022 seconds