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Phosphorus-31 Knigh shifts in amorphous nickel-phosphorus and nickel-cobalt-phosphorus alloys

Amorphous alloys of the form Ni(,1-x)P(,x) and (Ni(,1-y)Co(,y))(,1-x)P(,x) were prepared by two methods, electroplating (EP) and electroless deposition (EL). Two metastable phases of differing physical densities and NMR properties were noted, and analysed by measurement of the Knight Shifts, relaxation times, physical densities, etc. A comparison is made between the data and a hybridized band model which yields an expression for the enhanced susceptibility of the phosphorous valence band.

Identiferoai:union.ndltd.org:wm.edu/oai:scholarworks.wm.edu:etd-3586
Date01 January 1981
CreatorsGustafson, Paul Stuart
PublisherW&M ScholarWorks
Source SetsWilliam and Mary
LanguageEnglish
Detected LanguageEnglish
Typetext
Formatapplication/pdf
SourceDissertations, Theses, and Masters Projects
Rights© The Author

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