The syntheses of new classes of conjugated polymers are presented. The synthesis of novel alkyne bridged trispyrazolylmethane ligands, their coordination behavior and their crystallographic properties are studied. A series of functionalized poly(paraphenyleneethynylene)s, PPEs, are produced by click chemistry with post and pre-polymerization. Unpredictable solid-state polymerizations of defect free conjugated polythiophenes are investigated. Finally, by click chemistry aromatic diazides and aromatic diynes are coupled to produce a library of 1,2,3-triazoles and new conjugated polymers, poly(arylenetriazoline)s.
| Identifer | oai:union.ndltd.org:GATECH/oai:smartech.gatech.edu:1853/10440 |
| Date | 13 January 2006 |
| Creators | Bakbak, Selma |
| Publisher | Georgia Institute of Technology |
| Source Sets | Georgia Tech Electronic Thesis and Dissertation Archive |
| Language | en_US |
| Detected Language | English |
| Type | Dissertation |
| Format | 7684655 bytes, application/pdf |
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