In this study, reversed phase HPLC with dual UV photodiode (PDA) and fluorescence (FL) detection were used to investigate copper complexes with fulvic, caffeic, vanillic, salicylic, and adipic acids. Application of the RE method provided valuable information on the retention behavior and spectral characteristics of FA and model compounds. Even though the method was only applicable to VA, the use of the PDA detector allowed the UV-V is scanning of the separated peaks. This allowed the comparison between the UV-Vis spectra of uncomplexed species. The overall results provide an experimental framework for validation of the proposed Cu-humate interaction models.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc332502 |
| Date | 08 1900 |
| Creators | Liao, Jing-Piin |
| Contributors | Wu, Edward Ming-chi, 1938-, Pirtle, Robert M., Masaracchia, Ruthann A., Gracy, Robert W., Jacobson, Myron, Benjamin, Robert C. |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | ix, 171 leaves : ill., Text |
| Rights | Public, Liao, Jing-Piin, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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