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Syntheses and structures of copper and zinc complexes with N₃O donor ligands.

by Chan Sau Han. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. / Includes bibliographical references. / Abstracts in English and Chinese. / ABSTRACT --- p.i / 摘要 --- p.ii / ACKNOWLEDGMENT --- p.iii / CONTENTS --- p.iv / ABBREVIATIONS --- p.vi / Chapter CHAPTER 1 --- General Introduction / Chapter 1-A. --- Role of Copper in Biology --- p.1 / Chapter 1-B. --- A Brief Review on Radical Copper Proteins --- p.4 / Chapter 1-C. --- Objectives of This Work --- p.12 / Chapter 1-D. --- References --- p.13 / Chapter CHAPTER 2 --- Copper(II) and Zinc(II) Complexes containing N3O Tetradentate Ligands / Chapter 2-A. --- Introduction Results and Discussion --- p.14 / Chapter 2-B. --- Preparation of Tetradentate Ligands and Complexes --- p.27 / Chapter 2-C. --- Characterization --- p.36 / Chapter 2-D. --- Generation of Metal Phenoxyl Radical Species --- p.51 / Chapter 2-E. --- Summary --- p.57 / Chapter 2-F. --- References --- p.59 / Chapter CHAPTER 3 --- Copper(I) Complexes with N30 Tetradentate Ligands / Chapter 3-A. --- Introduction Results and Discussion --- p.62 / Chapter 3-B. --- Preparation of Copper(I) Complexes with N30 Tetradentate Ligands --- p.75 / Chapter 3-C. --- Characterization --- p.79 / Chapter 3-D. --- Reactivities of 86,87 and 88 toward Dioxygen --- p.88 / Chapter 3-E. --- Summary --- p.93 / Chapter 3-F. --- References --- p.94 / Chapter CHAPTER 4 --- Experimental Sections / Chapter 4-A. --- General Preparations and Physical Measurements --- p.97 / Chapter 4-B. --- Compounds Described in Chapter2 --- p.99 / Chapter 4-C. --- Compounds Described in Chapter3 --- p.113 / Chapter 4-D. --- Oxo-Transfer to Triphenylphosphine as Described in Chapter3 --- p.117 / Chapter 4-E. --- References --- p.119 / Chapter APPENDIX A --- 1H and13 C̐ưث1H ̐ưحNMR Spectra / Chapter A-1. --- Compounds Described in Chapter2 --- p.120 / Chapter A-2. --- Compounds Described in Chapter3 --- p.127 / Chapter APPENDIX B --- Crystallographic Data / Chapter B-1. --- X-ray Crystal Structure Data for Complexes in Chapter2 --- p.131 / Chapter B-2. --- X-ray Crystal Structure Data for Complexes in Chapter3 --- p.133 / Chapter APPENDIX C --- GC-MS Spectra / Chapter C-1. --- GC-MS Spectra for Standard Samples --- p.134 / Chapter C-2. --- GC-MS Spectra for the Reactions with Triphenylphosphine Described in Chapter3 --- p.136

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323519
Date January 2001
ContributorsChan, Sau Han., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, vi, 107 leaves : ill. (some col.) ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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