Copper and zinc are heavy metals commonly present in highway stormwater runoff. Discharge of these metals to surface waters inhabited by sensitive aquatic species including threatened and endangered salmonids has necessitated the need for improved treatment techniques. Although copper is of the greater toxicological concern, zinc is often present at concentrations several times higher than copper and may compete with copper during adsorptive treatment processes. In the current study, the ability biogenic fish-bone based alternative adsorbent, Apatite II™, for copper and zinc removal from synthetic stormwater runoff was evaluated. Batch experiments were employed to examine equilibrium removal and rapid small scale column tests (RSSCT) were used to simulate dynamic operation in continuous systems. In both batch and continuous systems, the release of phosphate and calcium were observed, and Apatite II™ achieved high removal efficiencies. The removal of copper and zinc was likely due to a combination of processes including adsorption, ion exchange and precipitation. Precipitation played a dominant role in copper removal and the release of phosphate and pH buffering appear to drive this process. While precipitation was also quite important for zinc removal, adsorptive removal also played a role. The findings from the current study provide a general understanding of the performance of copper and zinc removal from stormwater runoff using Apatite II™. / Graduation date: 2012
| Identifer | oai:union.ndltd.org:ORGSU/oai:ir.library.oregonstate.edu:1957/30386 |
| Date | 31 May 2012 |
| Creators | Huang, Hsiao-Wen |
| Contributors | Nason, J. A. |
| Source Sets | Oregon State University |
| Language | en_US |
| Detected Language | English |
| Type | Thesis/Dissertation |
Page generated in 0.0022 seconds