Acylation of cyclohexene can provide number of reaction products. Cyclohexene, 1-methylcyclohexene and 3-methylcyclohexene were acylated with propionic anhydride over diferent zeolite structures and molecular sieves. Cyclohexene acylation led to propionylcyclohexene. The major acylation products of 1-methylcyclohexene is 2-methyl-3-propionylcyclohexene. Reaction product of 3-methylcyclohexene acylation is 4-methyl-3-propionylcyklohexene and 3-methyl-2-propionylcyclohexene. The aim of acylation biphenyl with carboxylic acid anhydrides and chlorides was to prove reaction with the highest conversion of substrate. The highest biphenyl conversion was obtained with octanoyl chloride and hexanoic anhydride over zeolite USY (15). The highest selectivity to 4-acylbiphenyl was observed.
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:284896 |
| Date | January 2010 |
| Creators | Pavlatová, Jana |
| Contributors | Vohlídal, Jiří, Svoboda, Jan |
| Source Sets | Czech ETDs |
| Language | Czech |
| Detected Language | English |
| Type | info:eu-repo/semantics/masterThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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