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Attempted hydroformylation of triacetyl-D-glucal

Triacetyl-D-glucal, an unsaturated sugar has been prepared and submitted to the hydroformylation reaction, which is the addition of carbon monoxide and hydrogen to an unsaturated compound at high pressure and temperature. A cobalt catalyst is generally used, in this case, cobalt acetate tetrahydrate.
The mixture of products obtained was separated by column chromatography and distillation. The main products are probably triacetyl-D-deoxyglucose obtained by the addition of water to the starting material, 1,2-hydroglucal obtained by hydrogenation of the starting material, a small amount of the theoretical hydroformylation compound and varying amounts of the starting material. / Science, Faculty of / Chemistry, Department of / Graduate

Identiferoai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/40661
Date January 1955
CreatorsCameron, Christina Janet
PublisherUniversity of British Columbia
Source SetsUniversity of British Columbia
LanguageEnglish
Detected LanguageEnglish
TypeText, Thesis/Dissertation
RightsFor non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.

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