A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions. / Original publication is available at http://dx.doi.org/10.1039/C5DT03256C
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:rhodes/vital:7282 |
| Date | 07 October 2015 |
| Creators | Jiang, Yu, Li, Minzhi, Liang, Xu, Mack, John, Wildervanck, Martijn, Nyokong, Tebello, Qin, Mingfeng, Zhu, Weihua |
| Publisher | Royal Society of Chemistry |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Article |
| Format | 10 p., pdf |
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