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Fabrication and characterization of metallic glass foams by dealloying method

The processing and characterization of thin film metallic glasses (TFMGs) and bulk metallic glass foams (BMGFs), prepared by the dealloying corrosion process, have been studied. The TFMGs were fabricated by the co-sputtering with the Zr65Cu25Ti10 (wt%) alloy target and the pure Ta target. For BMG, there are two kinds of amorphous metallic powders adopted, namely, Zr53Cu30Ni9Al8, and Ti40Cu36Pd14Zr10. The Zr- and Ti-based powders were sintered at the temperature that Zr- and Ti-based powders overlap their supercooled regions. To fabricate the porous structure, these materials were selectively dissolved using electrochemical treatments in 0.1 M HNO3 solution. The glassy nature and the pore morphology of the corroded materials were confirmed by X-ray diffraction and scanning electron microscopy. In the current study, the pore size is about 10-30 £gm and the porosity volume faction is about 43%. By using different combinations of the powders size and volume fraction, the resulting pore size and porosity fraction can be upgraded to 200-500 £gm and 60-80%, respectively.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0904112-190600
Date04 September 2012
CreatorsLin, Wei-jau
ContributorsChung-Hwan Chen, J. C. Huang, Chehsin Lin
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageEnglish
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0904112-190600
Rightsuser_define, Copyright information available at source archive

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