Thesis advisor: Jeffery A. Byers / This dissertation covers the development of redox-switchable ring-opening polymerizations for the synthesis of copolymers of underutilized monomers. In Chapter one, the progress in the development of switchable methods for ring-opening polymerization and ring-opening copolymerizations. Chapter two describes a method for the redox-switchable copolymerization of L-lactide, propylene oxide and carbon dioxide. The benefits of this method are demonstrated through the facile synthesis of blocky and statistical copolymers of the three monomers. In Chapter three, a method for the redox-switchable polymerization of N-carboxyanhydrides is presented. A mechanistic analysis and copolymerizations of N-carboxyanhydrides and either lactones or epoxides follow the initial findings. Chapter four further expands the uses of N-carboxyanhydride redox-switchable polymerizations by immobilizing the catalysts onto semiconductor surfaces for the synthesis of surface bound polyamides. / Thesis (PhD) — Boston College, 2021. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Chemistry.
| Identifer | oai:union.ndltd.org:BOSTON/oai:dlib.bc.edu:bc-ir_109277 |
| Date | January 2021 |
| Creators | Thompson, Matthew Scott |
| Publisher | Boston College |
| Source Sets | Boston College |
| Language | English |
| Detected Language | English |
| Type | Text, thesis |
| Format | electronic, application/pdf |
| Rights | Copyright is held by the author, with all rights reserved, unless otherwise noted. |
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