The ayelodehydrogenation of 7-(1-naphthyl)benz [a] anthracene to dibenzo [a,e] perylene was accomplished in 38% yield using an aluminum chloride - stannic chloride catalyst. Attempts to reproduce or to improve this yield were not successful and thereafter the only product isolated was a low melting light orange solid which was postulated to be a hydrogenated intermediate. That the orange material could be converted to dibenzo [a,e] perylene upon treatment with palladiem on charcoal in p-eymene substantiated this postulation. / Master of Science
Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/43027 |
Date | 10 June 2012 |
Creators | Pavlik, James William |
Contributors | Chemistry, Vingiello, Frank A. |
Publisher | Virginia Tech |
Source Sets | Virginia Tech Theses and Dissertation |
Language | English |
Detected Language | English |
Type | Thesis, Text |
Format | 59 leaves, BTD, application/pdf, application/pdf |
Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
Relation | OCLC# 22537077, LD5655.V855_1961.P384.pdf |
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