Queenie Wai Yan Ip. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2003. / Includes bibliographical references (leaves 91-94). / Abstracts in English and Chinese. / Acknowledgements --- p.ii / Abstract --- p.iii / 摘要 --- p.v / List of Abbreviations --- p.xii / List of Compounds Synthesized --- p.xiii / Chapter CHAPTER 1 --- Syntheses and Characterizations of Pyrazyl-Linked Bis(l-Aza-Allyl) Alkali-Metal Complexes / Chapter 1.1. --- Introduction --- p.1 / Chapter 1.1.1. --- A General Review of 1-Aza-Allyl Ligands --- p.1 / Chapter 1.1.2. --- A General Review of Group 1 Alkali-Metal Complexes Containing Bis(l-Aza-Allyl) Ligands --- p.6 / Chapter 1.2. --- Objective --- p.9 / Chapter 1.3. --- Results and Discussion --- p.11 / Chapter 1.3.1. --- Preparation and Characterization of Pyrazyl-Linked Bis(l-Aza-Allyl) Di-Lithium Complex --- p.11 / Chapter 1.3.1.1. --- "A Modified Synthesis of Pyrazyl-Linked Bis(l-Aza-Allyl) Di-Lithium Complex [Li2{{N(SiMe3)C(But)C(H)}2C4H2N2-2,3}(THF)2]2 (1)" --- p.11 / Chapter 1.3.1.2. --- Physical and Spectroscopic Properties of Complex 1 --- p.11 / Chapter 1.3.1.3. --- Molecular Structure of Complex 1 --- p.12 / Chapter 1.3.2. --- Preparation and Characterization of Pyrazyl-Linked Bis(l-Aza-Allyl) Di-Sodium and Di-Potassium Complexes --- p.15 / Chapter 1.3.2.1. --- "Preparation of Pyrazyl-Linked Bis( 1 -Aza-Allyl) Di-Sodium complex [Na2{{N(SiMe3)C(But)C(H)}2C4H2N2-2,3}(THF)2]2 (2) and Di-Potassium Complex [K2{{N(SiMe3)C(But)C(H)}2C4H2N2-2,3}- (THF)3]2 (3)" --- p.15 / Chapter 1.3.2.2. --- Physical and Spectroscopic Properties of Complexes 2 and 3 --- p.15 / Chapter 1.3.2.3. --- Molecular Structures of Complexes 2 and 3 --- p.16 / Chapter 1.4 --- Experimental Section --- p.23 / Chapter 1.5 --- References --- p.25 / Chapter CHAPTER 2 --- Syntheses and Characterizations of Pyrazyl-Linked Bis(l-Aza-Allyl) Group 2 and 12 Metal Complexes / Chapter 2.1 --- Introduction --- p.29 / Chapter 2.1.1. --- A General Review of Group 2 Metal Complexes containing Bis(l-Aza-Allyl) Ligands --- p.29 / Chapter 2.1.2. --- A General Review of Group 12 Metal Complexes containing Bis(l-Aza-Allyl) Ligands --- p.32 / Chapter 2.2 --- Results and Discussion --- p.34 / Chapter 2.2.1. --- Preparation and Characterization of Pyrazyl-Linked Bis(l-Aza-Allyl) Di-Magnesium Complex --- p.34 / Chapter 2.2.1.1. --- "Preparation of Pyrazyl-Linked Bis(l-Aza-Allyl) Di-Magnesium Complex [Mg2{{N(SiMe3)C(But)C(H)}2C4H2N2-2,3}Br2(THF)4] (4).……" --- p.34 / Chapter 2.2.1.2. --- Physical and Spectroscopic Properties of Complex 4 --- p.34 / Chapter 2.2.1.3. --- Molecular Structure of Complex 4 --- p.35 / Chapter 2.2.2. --- Preparation and Characterization of Pyrazyl-Linked Bis(l-Aza-Allyl) Lithium Zincate Complex --- p.38 / Chapter 2.2.2.1. --- "Preparation of Pyrazyl-Linked Bis(l-Aza-Allyl) Lithium Zincate Complex [Zn2{{N(SiMe3)C(But)C(H)}2C4H2N2-2,3}Cl2(u-Cl)2Li2(THF)6] (5)" --- p.38 / Chapter 2.2.2.2. --- Physical and Spectroscopic Properties of Complex 5 --- p.39 / Chapter 2.2.2.3. --- Molecular Structure of Complex 5 --- p.39 / Chapter 2.2.3. --- Preparation and Characterization of Unexpected Cyclization Compound --- p.42 / Chapter 2.2.3.1. --- "Preparation of Unexpected Cyclization Compound [{Me2Si{NC(But)C(H)}}2C4H2N2-2,3] (6)" --- p.42 / Chapter 2.2.3.2. --- Physical and Spectroscopic Properties of Complex 6 --- p.43 / Chapter 2.2.3.3. --- Molecular Structure of Complex 6 --- p.44 / Chapter 2.2.4. --- Attempted Synthesis of Analogous Mercury Complex --- p.45 / Chapter 2.2.5. --- Comparison on Structures and Reactivities of Compounds 4-6 --- p.46 / Chapter 2.3. --- Experimental Section --- p.48 / Chapter 2.4. --- References --- p.50 / Chapter CHAPTER 3 --- Syntheses and Characterizations of Bis(Phosphoranoimido) Magnesium and Group 14 Metal Complexes / Chapter 3.1 --- Introduction --- p.52 / Chapter 3.1.1. --- A General Review of Functionalized Phosphoranoimine Ligands --- p.52 / Chapter 3.1.2. --- A General Review of Group 14 Metal Complexes Containing Bis(Phosphoranoimines) Ligands --- p.59 / Chapter 3.2. --- Objective --- p.61 / Chapter 3.3. --- Results and Discussion --- p.64 / Chapter 3.3.1. --- Preparation and Characterization of Bis(Phosphoranoimido) Magnesium Complexes --- p.64 / Chapter 3.3.1.1. --- "Preparation and Characterization of Bis(Phosphoranoimido) Magnesium Complexes [Mg{(Me3SiN=PR2CH)2C5H3N-2,6}THF] (R = Pri, 9; R = Ph, 10)" --- p.64 / Chapter 3.3.1.2. --- Physical and Spectroscopic Properties of Complexes 9 and 10 --- p.64 / Chapter 3.3.1.3. --- Molecular Structures of Complexes 9 and 10 --- p.65 / Chapter 3.3.2. --- Preparation and Characterization of Bis(Phosphoranoimido) Tin(II) and Lead(II) Complexes --- p.70 / Chapter 3.3.2.1. --- "Preparations and Characterizations of 1,3-Distannacyclobutane with Chlorotin(II) Alkyl Complex [{2-{Sn{C(Pri2P=NSiMe3)}}-6- {Sn{CH(Pri2p=NSiMe3)}Cl}}C5H3N]2 (11) and 1,3-Diplumbacyclobutane with bis(trimethylsilyI)amido Lead(II) Alkyl Complex [{2-{Pb{C(Pri2P=NSiMe3)}}-6-{Pb{CH(Pri2P=NSiMe3)}N(SiMe3)2}}- C5H3N]2 (12)" --- p.70 / Chapter 3.3.2.2. --- Physical and Spectroscopic Properties of Complexes 11 and 12 --- p.73 / Chapter 3.3.2.3. --- Molecular Structures of Complexes 11 and 12 --- p.74 / Chapter 3.3.3. --- Preparation and Characterization of Bis(Phosphoranoimido) Germanium(II) Enamido and Alkyl Complex --- p.79 / Chapter 3.3.3.1. --- Preparation and Characterization of Bis(Phosphoranoimido) Germanium(II) Enamido and Alkyl Complex [{2-CH(Pri2P=NSiMe3)-6-CH(Pri2P=NSiMe3)}C5H3NGe{2-{C(Pri2P=NSi Me3)Ge} -6-CH2(Pri2P=NSiMe3)} C5H3N] (13) --- p.79 / Chapter 3.3.3.2. --- Physical and Spectroscopic Properties of Complex 13 --- p.81 / Chapter 3.3.3.3. --- Molecular Structure of Complex 13 --- p.81 / Chapter 3.3.4. --- Comparison on Structures and Reactivities of Compounds 11-13 --- p.85 / Chapter 3.4. --- Experimental Section --- p.87 / Chapter 3.5. --- References --- p.91 / APPENDIX I / Chapter A --- General Experimental Procedures and Physical Measurement --- p.95 / Chapter B --- X-Ray Crystallography --- p.96 / APPENDIX II / Tables of Crystallographic Data and Refinement Parameters --- p.98
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_324466 |
| Date | January 2003 |
| Contributors | Ip, Queenie Wai Yan., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xiii, 104 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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