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Paramagnetic resonant-relaxation in potassium ferricyanide

Measurements of the spin-lattice relaxation time, T1, and spin-spin relaxation time, T2, of potassium ferricyanide diluted by potassium coba1ticyanide were made by the CW saturation method. Crystals of two concentrations of Fe3+ in K3Co(CN)6 were investigated: 0.5% and 1.0%. The results are the same for both concentrations to within the probable error. The mean relaxation times for the two concentrations are quoted to one significant figure, together with the probable errors: T1 =(1 +- 0.15) x 10-4 sec and T2 = (9 +- 0.4) x 10-9 sec. Calculations have been made to determine the angular dependence of the paramagnetic resonance spectra of potassium ferricyanide. Three graphs have been plotted which may be useful for comparison with future measurements.

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.103421
Date January 1961
CreatorsKipling, Arlin Lloyd
ContributorsWoonton, G.A. (Supervisor)
PublisherMcGill University
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Formatapplication/pdf
CoverageMaster of Science (Department of Physics)
RightsAll items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.
Relationalephsysno: 003530778, Theses scanned by McGill Library.

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