Solid residues are generated at various stages of metal production. Some of these residues still contain significant quantities of metals. In determining possible process routes for residues a detailed knowledge of the mineralogy (i.e. the minerals or phases present) is required. This thesis examines the mineralogical characteristics of four residues: copper smelter dust, jarosite residue and hot-acid-leach residue all from the metallurgical plant of Kidd Creek Mines Ltd., and low-acid-leach residue from the Canadian Electrolytic Zinc plant. / The methodology of characterization included the fractionation of the residues based on particle size, magnetic susceptibility and leachability in sulphuric acid. The fractions were analyzed by X-ray diffractometry and electron beam techniques. / A major phase in all the residues was zinc ferrite. The characterization of this phase showed that it does not have the stoichiometric composition of ZnFe$ sb2$O$ sb4$ but exhibits a variable composition of the type Zn$ sb{x}$Fe$ sb{3-x}$O$ sb4$. This variable composition corresponds to a measured variation in magnitude susceptibility of the ferrites. / Some treatment routes for these residues are examined; special emphasis was placed on the potential application of magnetic separation. The hot-acid-leach residue appeared the most amenable to magnetic separation.
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.75959 |
| Date | January 1988 |
| Creators | Lastra Quintero, Rolando |
| Publisher | McGill University |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Format | application/pdf |
| Coverage | Doctor of Philosophy (Department of Mining and Metallurgical Engineering.) |
| Rights | All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. |
| Relation | alephsysno: 000910001, proquestno: AAINL52458, Theses scanned by UMI/ProQuest. |
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