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Potential chemical remediation of mercury in recently impounded reservoirs

Several mitigation procedures have been proposed to limit the transfer of Hg and MeHg to aquatic organisms but most cannot be applied to large reservoirs such as those of northern Quebec for practical, economical, and environmental reasons. A better understanding of the diagenetic behaviour of Hg and methylmercury in aquatic environments has lead us to consider methods of enhancing natural processes which would either limit the mobility of Hg in flooded soils or its methylation. Different concentrations of iron oxide, iron shavings and ferrous ammonium sulphate were added to soil slurries in the presence or absence of calcite and gypsum. Mercury released to the supenatent solutions and methylmercury adsorbed to the slurry solids were monitored with time to determine the trapping efficiency of the different chemical additives under both reducing and oxygenated conditions. Whereas all three reagents limited the release of Hg(2+) to the supernatent solution when reducing conditions were allowed to develop in the slurries, ferrous ammonium sulphate appeared to be the most effective at limiting Hg methylation. (Abstract shortened by UMI.)

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.27286
Date January 1996
CreatorsBoiridy, Mia Ingrid.
ContributorsMucci, Alfonso (advisor)
PublisherMcGill University
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Formatapplication/pdf
CoverageMaster of Science (Department of Earth and Planetary Sciences.)
RightsAll items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.
Relationalephsysno: 001555949, proquestno: MQ29660, Theses scanned by UMI/ProQuest.

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