Air-Assisted Solvent Extraction (AASX) is a novel concept that uses a solvent-coated bubble to contact the organic and aqueous phases. The advantages over conventional solvent extraction (SX) are high solvent to aqueous contact area with reduced solvent volume and ease of phase separation due to the buoyancy imparted by the air core. This opens the way to treat dilute solutions (<1 g/L), such as effluents. / The novel contribution in this thesis is the production of solvent-coated bubbles by exploiting foaming properties of kerosene-based solvents. / The basic set-up is a chamber to generate foam which is injected through a capillary (orifice diameter 2.5 mm) to produce solvent-coated bubbles (ca. 4.4 mm) which release into the aqueous phase. This generates a solvent specific surface area of ca. 3000 cm-1, equivalent to solvent droplets of ca. 20 mum. Demonstrating the process on dilute Cu solutions (down to 25 mg/L), high aqueous/organic ratios (ca. 75:1) and extractions are achieved. The solvent readily disengages to accumulate at the surface of the aqueous solution. / The LIX family of extractants imparts some foaming to kerosene based solvents but D2EHPA does not. An extensive experimental program determined that 1.5 ppm silicone oil provided the necessary foaming action without affecting extraction or stripping efficiency, greatly expanding the range of solvents that can be used in AASX. / To complement the foam study, films on bubbles blown in solvent were examined by interferometry (film thickness) and infra-red spectroscopy (film composition). A "bound" solvent layer was identified with an initial thickness of ca. 2 - 4 mum, comparable to that determined indirectly (by counting bubbles in an AASX trial and measuring solvent consumption). The film composition appeared to be independent of film thickness as it decreased with time. / As a start to scaling up, the single bubble generation system was adapted by installing up to 8 horizontal capillaries. The bubbles generated were ca. 3.4 mm. Trials showed the multi-bubble set up was a simple replication of the individual bubble case. Preliminary analysis of kinetic data shows a fit to a first-order model.
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.102735 |
| Date | January 2006 |
| Creators | Tarkan, Haci Mustafa. |
| Publisher | McGill University |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Format | application/pdf |
| Coverage | Doctor of Philosophy (Department of Mining, Metals and Materials Engineering.) |
| Rights | © Haci Mustafa Tarkan, 2006 |
| Relation | alephsysno: 002569733, proquestno: AAINR27847, Theses scanned by UMI/ProQuest. |
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