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Effect of Ca as a modifier in hypoeutectic Al-Si alloys

Modification of the eutectic silicon in Al-Si alloys is traditionally performed by sodium and strontium addition. Although not traditionally used as a modifier, calcium also has the potential to modify the eutectic silicon in Al-Si alloys. Metallographic observation and thermal analysis studies in A357 alloy indicate that. when the cooling rate is quite low. Ca modifies the eutectic silicon. but the effect of Ca as a modifier is not as strong as is Na or Sr. When the cooling rate is high, a fully modified structure can be obtained with calcium. Recovery of Ca in the melt is high and certain. It does not fade with long holding times. Moreover, a premodified ingot can be used, and even when such all ingot is remelted repeatedly there is no calcium loss. / Calcium does increase porosity in castings. In general modification treatment with Ca improves mechanical properties, especially elongation. / Calcium adversely interacts with strontium and reduces the ability of strontium as a modifier. Microstructural and thermal analysis studies show that Ca has a deleterious effect on Sr-modified castings and vice versa. (Abstract shortened by UMI.)

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.20492
Date January 1998
CreatorsAbdollahi, Ahmad.
PublisherMcGill University
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Formatapplication/pdf
CoverageMaster of Engineering (Department of Mining and Metallurgical Engineering.)
RightsAll items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.
Relationalephsysno: 001610272, proquestno: MQ43991, Theses scanned by UMI/ProQuest.

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