A solution calorimeter was constructed with a temperature range of one degree in the region of 25°C. The precision of the calorimeter was about 0.3%. The heats of reaction of the following silver ethylenediamine complexes were measured: Ag(en)⁺, Ag₂(en)₂⁺⁺, Ag(en)₂⁺, and AgHen⁺⁺. With the formation constants determined by Schwarzenbach (6), the respective entropies were calculated. Enthalpy and entropy data for the Ag(en)⁺, Ag₂(en)₂⁺⁺, and Ag(en) ₂⁺ complexes are reasonable. The data for the AgHen⁺⁺ complex seems anomalous. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/74555 |
| Date | January 1963 |
| Creators | Jesser, Richard Alexander |
| Contributors | Chemistry |
| Publisher | Virginia Polytechnic Institute |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | en_US |
| Detected Language | English |
| Type | Thesis, Text |
| Format | 55 leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 21793762 |
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