This communication reports a unique ultra-large sheet formation through hierarchical self-assembly of a rod–coil graft copolymer containing a rigid polyphenylene backbone and flexible poly(ethylene oxide) (PEO) side chains. The hierarchical self-assembly process involved a distinctive morphological transition of 1D helical to 2D superstructures. The graft copolymer offers a new chance for the challenging bottom-up fabrication of ultra-large self-assembled nanosheets in solution, as well as a novel system for fundamental studies on 2D self-assembly of polymers.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-225638 |
| Date | 17 July 2017 |
| Creators | Huang, Yinjuan, Yuan, Rui, Xu, Fugui, Mai, Yiyong, Feng, Xinliang, Yan , Deyue |
| Contributors | Royal Society of Chemistry, |
| Publisher | Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:article |
| Format | application/pdf |
| Source | Polymer Chemistry (2016), 7(6). S. 1234-1238. ISSN: 1759-9962. DOI: 10.1039/C5PY01969A. |
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