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Quenching runaway reactions : hydrodynamics and jet injection studies for agitated reactors with a deformed free-surface

To quench a thermal runaway reaction in a chemical rector, an efficient approach is the introduction of a small quantity of a liquid inhibiting agent, named a “killer”, into the mixing vessel. In this thesis, an experimental approach has been coupled tightly with numerical modelling using Computational Fluid Dynamics (CFD). The first part of this thesis is devoted to a study of the hydrodynamics of partially-baffled mixing vessels, including the free-surface deformation caused by the central vortex. The use of an inhomogeneous, multiphase approach allowed simulation of the free-surface deformation. The capability of this novel method was demonstrated by very good agreement between the numerical predictions and experimental data. In the second part, liquid jet injection at the free-surface was coupled with the vessel hydrodynamics. Numerical results, obtained using an Eulerian-Lagrangian approach, have again shown good agreement with experimental data. These results allowed the jet trajectory to be modelled and its penetration into the agitated vessel was quantified. New mixing criteria were introduced that are specific to this application. Finally, the numerical methods validated at the pilot scale were applied at the industrial scale and allowed the proposal of practical improvements to the safety of the synthesis reactors studied

Identiferoai:union.ndltd.org:univ-toulouse.fr/oai:oatao.univ-toulouse.fr:7658
Date06 December 2007
CreatorsTorré, Jean-Philippe
ContributorsInstitut National Polytechnique de Toulouse - INPT (FRANCE), Laboratoire de Génie Chimique - LGC (Toulouse, France)
Source SetsUniversité de Toulouse
LanguageEnglish
Detected LanguageEnglish
TypePhD Thesis, PeerReviewed, info:eu-repo/semantics/doctoralThesis
Formatapplication/pdf
Rightsinfo:eu-repo/semantics/openAccess
Relationhttp://ethesis.inp-toulouse.fr/archive/00000589/, http://oatao.univ-toulouse.fr/7658/

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