Nanostructured fayalite (α-Fe2SiO4) with a large volume fraction of interfaces is synthesized for the first time via single-step mechanosynthesis, starting from a 2α-Fe2O3 + 2Fe + 3SiO2 mixture. The nonequilibrium state of the as-prepared silicate is characterized by the presence of deformed polyhedra in the interface/surface regions of nanoparticles. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-138859 |
| Date | 03 April 2014 |
| Creators | Šepelák , Vladimir, Myndyk, Maxym, Fabián, Martin, Da Silva, Klebson L., Feldhoff, Armin, Menzel, Dirk, Ghafari, Mohammad, Hahn, Horst, Heitjans, Paul, Becker, Klaus D. |
| Contributors | Royal Society of Chemistry, |
| Publisher | Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:article |
| Format | application/pdf |
| Source | Chemical communications 2012;48:11121-11123, ISSN: 1359-7345 |
| Relation | dcterms:isPartOf:Mechanochemistry: fundamentals and applications in synthesis |
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