by Ka-Wo Poon. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1999. / Includes bibliographical references (leaves 113-120). / Abstracts in English and Chinese. / ABSTRACT --- p.i / ACKNOWLEDGMENT --- p.iii / CONTENTS --- p.iv / LIST OF FIGURES --- p.vi / LIST OF TABLES --- p.x / ABBREVIATIONS --- p.xi / Chapter 1. --- INTRODUCTION --- p.1 / Chapter 1.1 --- General Background of Tetrapyrrole Derivatives --- p.1 / Chapter 1.2 --- Electronic Interactions in Systems with Multiple Redox Sites --- p.8 / Chapter 1.2.1 --- Electronic Interactions in One-dimensional Systems --- p.9 / Chapter 1.2.2 --- Electronic Interactions in Three-dimensional Systems --- p.12 / Chapter 1.3 --- Ferrocene-containing Tetrapyrrole Derivatives --- p.22 / Chapter 1.3.1 --- Ferrocene-containing Porphyrins --- p.22 / Chapter 1.3.2 --- Ferrocene-containing Porphyrazines --- p.29 / Chapter 1.3.3 --- Ferrocene-containing Phthalocyanines --- p.30 / Chapter 2. --- RESULTS AND DISCUSSION --- p.38 / Chapter 2.1 --- Ferrocenylphthalocyanines with Oxyethylene Linkers --- p.38 / Chapter 2.1.1 --- Synthesis and Characterization --- p.38 / Chapter 2.1.1.1 --- Preparation of Tetrakis(2-ferrocenylethoxy)- phthalocyaninatozinc(II) (55) --- p.38 / Chapter 2.1.1.2 --- Preparation of Octakis(2-ferrocenylethoxy)- phthalocyaninatozinc(II) (62) --- p.43 / Chapter 2.1.1.3 --- Preparation of Metal Free Hexadecakis(2- ferrocenylethoxy)phthalocyanine (65) --- p.49 / Chapter 2.1.2 --- Electronic Absorption Spectra --- p.52 / Chapter 2.1.3 --- Electrochemical Studies --- p.60 / Chapter 2.2 --- Ferrocenyl Tetrapyrroles with Ethynyl Linkers --- p.68 / Chapter 2.2.1 --- Synthesis and Characterization --- p.68 / Chapter 2.2.1.1 --- Preparation of Octakis(ferrocenylethynyl)- phthalocyaninatozinc(II) (83) --- p.71 / Chapter 2.2.1.2 --- Preparation of Octakis(ferrocenylethynyl)- Naphthalocyaninatozinc(II) (87) --- p.76 / Chapter 2.2.1.3 --- "Preparation of 5,15-bis(ferrocenylethynyl)- 10,20-diphenylporphyrinatonickel(II) (90)" --- p.81 / Chapter 2.2.2 --- Electrochemical Studies --- p.84 / Chapter 2.3 --- Conclusion --- p.92 / Chapter 3. --- EXPERIMENTAL SECTION --- p.93 / Chapter 3.1 --- General Methods --- p.93 / Chapter 3.2 --- Physical Measurements --- p.93 / Chapter 3.3 --- Synthesis of Ferrocenylphthalocyanines with Oxyethylene Linkers --- p.95 / Chapter 3.4 --- Synthesis of Ferrocenyl Tetrapyrrole Derivatives with Ethynyl Linkers --- p.105 / Chapter 4. --- REFERENCES --- p.111 / Chapter APPENDIX A --- 1H NMR spectra of dinitriles --- p.121 / Chapter APPENDIX B --- 13C̐ưث1H }NMR spectra of dinitriles --- p.126
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_322845 |
| Date | January 1999 |
| Contributors | Poon, Ka-Wo., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xii, 129 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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