Cotton possesses many characteristics that make it desirable to the consumer, and this has resulted in its usage in a broad range of products. Cotton, however, is a flammable material that is easily ignited and rapidly consumed. The flame retardant treatment of cotton is, therefore, an important textile process that has received wide attention over many years. There are a number of commercial flame retardant treatments available for cotton, the most common being phosphate-based. These treatments, however, often have drawbacks or have a negative impact on the desirable properties of the fibre and the challenge still exists for designing better flame retardant products and systems that are durable and have limited impact on fibre properties. The study considers the application of the sol-gel as a coating on fabric that was pre-treated with a phosphate-based flame retardant or as a means for applying a phosphate-based flame retardant. Both treatment methods were found to be suitable for imparting flame resistance to the fabric. The effect of various phosphate-based flame retardants on flammability and fabric properties such as colour, handle and strength was investigated and it was shown that a diammonium phosphate and urea combination gave the best flame resistance. In this regard, a flame resistance was achieved with a lower amount of phosphorous than was used in similar conventional treatments. The durability of the coating to rinsing with water and soaping with a detergent was also investigated. It was found that the flame resistance was lost after rinsing or soaping but the prevention of afterglow combustion was retained. It was shown that the preparatory treatment of the fabric influenced the sol-gel coating process and the flammability of the fabric. Mercerisation and bleaching of the fabric increased the “wet pick-up” during the coating process and improved the flame resistance. The influence of various factors was also investigated in further detail. The ratio of the sol-gel components, the delay after coating prior to drying (hang time) and the curing time were investigated using an experimental design. The curing time and the ratio of components in the sol-gel were shown to have the greatest influence on fabric properties and fabric flammability. It was shown that there is a trade-off between the desired high level of fabric flame resistance and preserving the inherent properties of the fabric such as colour, handle and strength.
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:nmmu/vital:10451 |
| Date | January 2007 |
| Creators | Chapple, Stephen Anthony |
| Publisher | Nelson Mandela Metropolitan University, Faculty of Science |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Thesis, Masters, MTech |
| Format | x, 114 leaves, pdf |
| Rights | Nelson Mandela Metropolitan University |
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