The new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, infrared, ¹H and ¹³C NMR spectroscopy, melting point and mass spectrometry. The new heterodinuclear complex [Cp(CO)₂Fe(CH₂)₄Ru(CO)₂Cp] has been synthesised by the reaction of [CpFe(CO)₂(CH₂)₄I] with Na[CpRu(CO)₂] and characterised by all the above mentioned techniques.
Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:uct/oai:localhost:11427/21938 |
Date | January 1988 |
Creators | Finch, Karol Paula |
Contributors | Moss, John R, Jackson, Graham Ellis |
Publisher | University of Cape Town, Faculty of Science, Department of Chemistry |
Source Sets | South African National ETD Portal |
Language | English |
Detected Language | English |
Type | Master Thesis, Masters, MSc |
Format | application/pdf |
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