This work constitutes a fundamental study of the interaction between soluble sulphide,copper (II) oxide and cerussite particles in the presence of Ca²⁺ ,Mg²⁺ starch , gum arabic and Triton X- IOO . A detailed investigation of the effect of pH of the system on the rate of sulphide uptake was made . In addition , the structural form of the surface precipitat.es were determined with the aid of scanning electron microscopy . On the basis of these results , it was concluded that adsorption of sulphide on cerussite in the presence or absence of Ca²⁺ starch, gum arabic and Triton X-IOO could either lead to the formation of a non-uniform or a uniform sulphide layer depending on the experimental conditions . However , the interaction of copper (II) · oxide wi th soluble sulphide in the presence or absence of the above mentioned species always led to the formation or a non-uniform sulphide layer . Preliminary experiments of the interaction between xanthate and sulphidized surface showed that oxide surface covered with metal sulphide layer reacts with less xanthate than the free oxide surface.
Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:rhodes/vital:4296 |
Date | 28 February 2013 |
Creators | Ramagwede, Mudzimba Hubert |
Publisher | Rhodes University, Faculty of Science, Chemistry |
Source Sets | South African National ETD Portal |
Language | English |
Detected Language | English |
Type | Thesis, Masters, MSc |
Format | 160 p., pdf |
Rights | Ramagwede, Mudzimba Hubert |
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