by Lawrence Tin-chi Law. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. / Includes bibliographical references (leaves 96). / acknowledgements --- p.iii / ABSTRACT --- p.iv / CONTENTS --- p.v / ABBREVIATION --- p.vii / Chapter CHAPTER I --- METALLATION OF 8-METHYLQUINOLINE / Chapter 1.1 --- INTRODUCTION --- p.1 / Chapter 1.1.1 --- A Brief Review of Metal-Alkyl Chemistry --- p.1 / Chapter 1.1.2 --- General Considerations --- p.2 / Chapter 1.1.3 --- 8-Methylquinoline as Ligand Precursor --- p.8 / Chapter 1.1.4 --- Metallations by Organolithium Compounds --- p.9 / Chapter 1.1.5 --- Other Methods for Metallations --- p.16 / Chapter 1.1.6 --- Aim of the Present Work --- p.21 / Chapter 1.2 --- RESULTS AND DISCUSSION --- p.24 / Chapter 1.2.1 --- Reactions of 8-Methylquinoline with Organolithium Reagents --- p.26 / Chapter 1.2.2 --- Synthesis of Grignard Reagent --- p.35 / Chapter 1.2.3 --- Attempted Metal-Halogen Exchange Reaction at Low Temperature --- p.39 / Chapter 1.2.4 --- Metallation of 8-methylquinoline by Lithium Diisopropylamide --- p.40 / Chapter 1.3 --- EXPERIMENTAL FOR CHAPTER I --- p.43 / Chapter 1.4 --- REFERENCES FOR CHAPTER I --- p.53 / Chapter CHAPTER II --- SYNTHESIS AND CHARACTERISATION AND STRUCTURE OF SOME MAIN GROUP 14 ALKYLS / Chapter 2.1 --- INTRODUCTION --- p.58 / Chapter 2.1.1 --- General Aspects of Group 14 Organometallic Compounds --- p.58 / Chapter 2.1.2 --- Group 14 Organometallic Confounds --- p.59 / Chapter 2.1.3 --- Subvalent Group 14 Metal Alkyls --- p.63 / Chapter 2.2 --- RESULTS AND DISCUSSION --- p.67 / Chapter 2.2.1 --- Synthesis of Five Co-ordinated Tin (IV) Compound --- p.67 / Chapter 2.2.2 --- Molecular Structure of [Sn{8-(CHSiMe3)C9H6N}Ph2Cl] --- p.70 / Chapter 2.2.3 --- Synthesis of Group 14 Subvalent Metal Complexes --- p.74 / Chapter 2.3 --- EXPERIMENTAL FOR CHAPTER II --- p.76 / Chapter 2.4 --- REFERENCES FOR CHAPTER II --- p.79 / Chapter CHAPTER III --- SYNTHESIS AND CHARACTERISATION OF SOME GROUP 12 (ZINC AND CADMIUM) METAL DIALKYLS / Chapter 3.1 --- INTRODUCTION --- p.81 / Chapter 3.1.1 --- A General Aspect of Group 12 Organometallics --- p.81 / Chapter 3.2 --- RESULTS AND DISCUSSION --- p.88 / Chapter 3.2.1 --- Synthesis of Group 12 Organometallic Confounds --- p.88 / Chapter 3.2.2 --- Molecular Structure of [Cd{8-(CHSiMe3)C9H6N}(tmeda)Cl] --- p.91 / Chapter 3.3 --- EXPERIMENTAL FOR CHAPTER III --- p.93 / Chapter 3.4 --- REFERENCES FOR CHAPTER III / APPENDIX I / Chapter 1. --- GENERAL PROCEDURES --- p.97 / Chapter 2. --- PHYSICAL AND ANALYTICAL MEASUREMENTS --- p.100 / APPENDIX II / LIST OF SELECTED 1H NMR SPECTRA --- p.101
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_318138 |
| Date | January 1993 |
| Contributors | Law, Tin-chi., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Publisher | Chinese University of Hong Kong |
| Source Sets | The Chinese University of Hong Kong |
| Language | English |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, vii, 101, [8] leaves ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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