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Polyethylene-layered double hydroxide and montmorillonite nanocomposites: Thermal, mechanical and flame retardance properties.

The effect of incorporation two clays; layered double hydroxides (LDH) and montmorillonite layered silicates (MLS) in linear low density polyethylene (PE) matrix was investigated. MLS and LDH were added of 5, 15, 30 and 60 weight percent in the PE and compounded using a Brabender. Ground pellets were subsequently compression molded. Dispersion of the clays was analyzed using optical microscopy, SEM and XRD. Both the layered clays were immiscible with the PE matrix and agglomerates formed with increased clay concentration. The thermal properties were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Both clays served as nucleation enhancers increasing recrystallization temperatures in the composites. Flame retarding properties were determined by using the flammability HVUL-94 system. LDH indicated better flame retarding properties than MLS for PE. The char structure was analyzed by environmental scanning electron microscopy. Mechanical properties were studied by tensile testing and Vickers microhardness testing apparatus.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc6087
Date05 1900
CreatorsKosuri, Divya
ContributorsD'Souza, Nandika Anne, 1967-, Brostow, Witold, 1934-, Scharf, Thomas W., Dharia, Amit
PublisherUniversity of North Texas
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
FormatText
RightsPublic, Copyright, Kosuri, Divya, Copyright is held by the author, unless otherwise noted. All rights reserved.

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